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6th September 2017, Heerlan

Two-part DSM design for hydrogen storage

Heerlan, Netherlands-headquartered Royal DSM’s Engineering Plastics business is introducing a new material solution for high-pressure composite tanks for hydrogen storage.

Hydrogen tanks are the next step in fuel storage, the company says, and as such, storage is a key enabling technology for advancing hydrogen and fuel cell technologies in applications that include stationary power, portable power and transportation.

DSM is working to apply its materials expertise to make safe, effective and very lightweight hydrogen tanks. © Royal DSM

Hydrogen has the highest energy per mass of any fuel. One kg of hydrogen is equivalent to 33.3 kWh, which means it delivers three times more energy than conventional fuel. But hydrogen’s low ambient temperature density results in a low energy per unit volume. This requires the development of advanced storage methods that have the potential for higher energy density.

DSM is working to apply its materials expertise to make safe, effective and very lightweight hydrogen tanks.

“We had already developed this technology for compressed natural gas (CNG) tanks, and now we are testing the same material and design principles for hydrogen tanks to meet the needs of the automotive industry,” said Bert Keestra, application development engineer at DSM.

The two-part tank design features a proven, blow moulded liner made of Akulon Fuel Lock, a polyamide 6-based engineering plastic with a very high barrier to hydrocarbons. The tank can then potentially be further reinforced by wrapping it in unidirectional (UD) continuous fibre-reinforced thermoplastic tapes made of EcoPaXX polyamide 410. This combination of commercially available materials has already proven to be very effective in CNG tanks, and DSM is now actively testing the concept in hydrogen tanks.

The two-part tank design features a proven, blow moulded liner made of Akulon Fuel Lock. © Royal DSM

The result would be the lightest-weight plastic tank available for hydrogen storage applications. Reducing weight is key, since every 10kg removed from a vehicle roughly translates into a reduction in CO2 emissions from the vehicle on the road of one gram per km.

For the liner, Akulon Fuel Lock greatly reduces weight compared to metal. It also offers improved permeation compared to polyolefin liners, meaning that the gas stays in the tank. The liner material is 100% recyclable and safe, with no debuckling.

Furthermore, the material is optimized to remain ductile and tough, even at extremely low temperatures (–40°C). This was important for CNG, but is even more vital for hydrogen storage, as the working pressures are much higher.

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